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包覆型纳米铜-银双金属粉研究
引用本文:廖辉伟,李 翔,彭汝芳,王兴明.包覆型纳米铜-银双金属粉研究[J].无机化学学报,2003,19(12):1327-1330.
作者姓名:廖辉伟  李 翔  彭汝芳  王兴明
作者单位:西南科技大学材料科学与工程学院,绵阳,621002
基金项目:大学青年预研基金资助项目(No.01ZK023001)。
摘    要:目前,导电胶或者电磁波屏蔽涂料用的导电性填料主要有三类,一是铜粉,二是银粉,三是铜-银双金属粉。铜粉具有来源广、价格低廉、导电性好等优点,但其抗氧化性能弱;银粉导电性与抗氧化性好,但其资源日益匮乏。大量的研究试图通过对铜粉进行表面改性来提高其性能。表面改性有两种方法,一是包膜处理,用SiO2溶胶处理铜粉,铜粉抗氧化性能提高,但其表面导电性能大大降低犤1犦;另一类方法是在铜粉表面覆盖一层导电性能与抗氧化性能均佳的银或金而制成双金属粉末犤2~5犦。制取高性能的铜-银双金属粉是该领域的研究重点。目前获得铜-银双金属粉的方…

关 键 词:铜烂版废液  化学镀  铜-银双金属粉  包覆结构
修稿时间:2003年5月5日

Study on Ag coating Cu Nano Bimetallic Powders
LIAO Hui-Wei,LI Xiang,PENG Ru-Fang and WANG Xing-Ming.Study on Ag coating Cu Nano Bimetallic Powders[J].Chinese Journal of Inorganic Chemistry,2003,19(12):1327-1330.
Authors:LIAO Hui-Wei  LI Xiang  PENG Ru-Fang and WANG Xing-Ming
Institution:College of Material Science and Engineering of the Southwest Technology University, Mianyang 621000,College of Material Science and Engineering of the Southwest Technology University, Mianyang 621000,College of Material Science and Engineering of the Southwest Technology University, Mianyang 621000 and College of Material Science and Engineering of the Southwest Technology University, Mianyang 621000
Abstract:The resource comes from waste cupric liquor produced in the process of manufacturing printed circuit board(PCB). In the liquid phase, we get high pureness and excellent property nano-Cu with the hydrazine dydrate as the reducer and the PVP and OP-10 as the dispersant. After the nano-Cu is sensitized and acted, the nano Cu-Ag Bimetallic Powders are got through 5% PVP and OP-10 are went into the plating solution and they are chemic plating. It is stated by the experimentation result that the powders can substitute Ag as the padding of conduction coating or shield coating.
Keywords:coppery waste liquid    chemically plating    Cu-Ag bimetallic powders    full-package structure
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