| 茂锆载体催化剂下的乙烯／辛烯共聚及聚合物的^13C NMR研究 |
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| 引用本文： | 刘胜生,于广谦. 茂锆载体催化剂下的乙烯／辛烯共聚及聚合物的^13C NMR研究[J]. 应用化学, 1996, 13(4): 110-112 |
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| 作者姓名： | 刘胜生 于广谦 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 茂锆载体催化剂下的乙烯／辛烯共聚及聚合物的~（１３）ＣＮＭＲ研究刘胜生，于广谦，黄葆同（中国科学院长春应用化学研究所长春１３００２２）关键词茂锆载体催化剂，共聚，序列分布，~（１３）ＣＮＭＲ由于茂锆催化剂具有高活性，单一活性中心等特点［１，２］，并且能...
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| 关 键 词： | 催化剂 共聚 NMR 乙烯 辛烯 锆 |
| 收稿时间： | 1995-10-17 |
Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the 13C NMR Analysis of Copolymers |
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| Liu Shengsheng,Yu Guangqian,Huang Baotong. Ethylene/Octene Copolymerization with Supported Zirconocene Catalysts and the 13C NMR Analysis of Copolymers[J]. Chinese Journal of Applied Chemistry, 1996, 13(4): 110-112 |
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| Authors: | Liu Shengsheng Yu Guangqian Huang Baotong |
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| Abstract: | Copolymerization of ethylene/octene_1 was investigated by using two types of supported zirconocene catalysts, Zr/MAO/SiO_2 and Zr/MAO/SAA,where SiO_2 and poly(styrene-acrylamide ) (SAA) were used as carriers respectively. The results showed that the catalysts have high copolymerization ability. The triad sequence distribution and mean sequence lengths of monomers in the copolymers have been calculated by 13C NMR data. |
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| Keywords: | supported zirconocene catalyst copolymerization sequence distribution 13C NMR |
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