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Hydrophosphonylation of alkenes or nitriles by double radical transfer mediated by titanocene/propylene oxide |
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| Authors: | Camille MidrierMathias Lantsoght Jean-Noël VolleJean-Luc Pirat David Virieux Christian V Stevens |
| Institution: | a Institut Charles Gerhardt - UMR 5253, Architecture Moléculaire et Matériaux Nanostructurés, Ecole Nationale Supérieure de Chimie de Montpellier, 8, rue de l’Ecole Normale, 34296 Montpellier Cedex 5, France b Department of Sustainable Organic Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, B-9000 Gent, Belgium |
| Abstract: | Hydrophosphonylation reactions have emerged as efficient processes for the functionalization of alkenes or alkynes. Synthesis of alkylphosphonates was achieved by an original double radical transfer mediated by titanocene and propylene oxide. By the same way, nitriles which are considered as inert functions in radical process lead to aminobisphosphonates. |
| Keywords: | Radical Titanocene Hydrophosphonylation Alkenes Nitriles |
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