Anomalous effect of nitrogen on side-chain alkylation of toluene with methanol over solid bases |
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| Authors: | K. Tanabe O. Takahashi H. Hattori |
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| Affiliation: | (1) Department of Chemistry, Faculty of Science, Hokkaido University, 060 Sapporo, Japan |
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| Abstract: | The alkylation of toluene with methanol was carried out at 500°C over various base catalysts. The activity of MgO was found to be highest when treated specially with nitrogen. The effect of nitrogen was anomalously large, 8, 8% ethylbenzene and 2.3% styrene being formed.
                 500°C       .      MgO,  .   : 8,8%  2,3% .
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