Microwave-assisted synthesis and photoluminescence of MMoO4 (M=Ca,Ba) particles via a metathetic reaction

MMoO₄ (M=Ca, Ba) particles were synthesized by a metathetic reaction in ethylene glycol assisted by cyclic microwave irradiation followed by further heat-treatment. The MMoO₄ (M=Ca, Ba) particles were well crystallized after heat-treatment at 400–600 °C for 3 h. The microstructures exhibited fine morphologies with sizes of 0.5–1 μm and 1.5–2 μm for the CaMoO₄ and BaMoO₄ particles, respectively. The synthesized MMoO₄ (M=Ca, Ba) particles were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. The optical properties were examined by photoluminescence emission and Raman spectroscopy.