A model study of intramolecular energy transfer in polyatomic molecular reactions |
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| Authors: | Meishan Zhao |
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| Affiliation: | (1) The James Franck Institute and Department of Chemistry, The University of Chicago, 60637 Chicago, IL, USA |
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| Abstract: | ![]()
Summary This paper reports a model study of intramolecular energy transfer in unimolecular isomerization reaction of cyclobutanone. The calculations of intramolecular energy flow were carried out using the theory of Gray and Rice as extended by Zhao and Rice. The results of the calculations are compared to those of local Lyapunov function analysis, and the agreement is found to be uniformly good. |
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| Keywords: | Nonlinear Dynamics Intramolecular energy transfer Isomerization Lyapunov exponent Cyclobutanone |
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