Characterization of Metallo-Supramolecular Systems by MALDI-TOF Mass Spectrometry |
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Authors: | Ulrich S. Schubert Christian Eschbaumer |
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Affiliation: | (1) Lehrstuhl für Makromolekulare Stoffe, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany |
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Abstract: | MALDI-TOF mass spectrometry was used for the characterization of metallo-supramolecular coordination arrays with molecular weights between 500 and 4000 g/mol. The stepwise loss of the counterions was used as an additional fingerprint for the investigated species. The isotope pattern yielded further information, especially in combination with simulations. |
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Keywords: | MALDI-TOF-MS supramolecular chemistry metal coordination array characterization in the solid state |
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