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Critical exponents,hyperscaling, and universal amplitude ratios for two- and three-dimensional self-avoiding walks
Authors:Bin Li  Neal Madras  Alan D Sokal
Institution:(1) Debt and Equity Markets Group, Merrill Lynch, World Financial Center, 10281-1315 New York, New York;(2) Department of Physics, New York University, 10003 New York, New York;(3) Department of Mathematics and Statistics, York University, M3J 1P3 North York, Ontario, Canada
Abstract:We make a high-precision Monte Carlo study of two- and three-dimensional self-avoiding walks (SAWs) of length up to 80,000 steps, using the pivot algorithm and the Karp-Luby algorithm. We study the critical exponentsv and 2Delta 4gamma as well as several universal amplitude ratios; in particular, we make an extremely sensitive test of the hyperscaling relationdv = 2Delta 4gamma. In two dimensions, we confirm the predicted exponentv=3/4 and the hyperscaling relation; we estimate the universal ratios <R g 2 >/<R e 2 >=0.14026±0.00007, <R m 2 >/<R e 2 >=0.43961±0.00034, and PSgr*=0.66296±0.00043 (68% confidence limits). In three dimensions, we estimatev=0.5877±0.0006 with a correctionto-scaling exponentDelta 1=0.56±0.03 (subjective 68% confidence limits). This value forv agrees excellently with the field-theoretic renormalization-group prediction, but there is some discrepancy forDelta 1. Earlier Monte Carlo estimates ofv, which were ap0.592, are now seen to be biased by corrections to scaling. We estimate the universal ratios <R g 2 >/<R e 2 >=0.1599±0.0002 and PSgr*=0.2471±0.0003; since PSgr*>0, hyperscaling holds. The approach to PSgr* is from above, contrary to the prediction of the two-parameter renormalization-group theory. We critically reexamine this theory, and explain where the error lies. In an appendix, we prove rigorously (modulo some standard scaling assumptions) the hyperscaling relationdv = 2Delta 4gamma for two-dimensional SAWs.
Keywords:Self-avoiding walk  polymer  critical exponent  hyperscaling  universal amplitude ratio  second virial coefficient  interpenetration ratio  renormalization group  two-parameter theory  Monte Carlo  pivot algorithm  Karp-Luby algorithm
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