Effect of Axial Ligands on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex |
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| Authors: | CHEN Xin-Bin GUI Ming-De ZHU Shen-Jie |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071 |
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| Abstract: | There are many dimetalloenzymes in nature1]. To mimic these enzymes, we synthesized a new dimanganese Schiff base complex-BisN,N'-ethylene-2,2,-(phenylmethylene)-bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese Mn2L (shown in Fig.1). Its structure was confirmed by IR, UV-Vis, 1HNMR and elemental analysis. It can catalyze monooxygenation of cyclohexane with PhIO as an oxidant. |
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