| 新奇二茂铁甲基氮C60衍生物的合成、结构 |
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| 引用本文： | 朱应怀,宋礼成.新奇二茂铁甲基氮C60衍生物的合成、结构[J].高等学校化学学报,1998,19(Z1):336. |
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| 作者姓名： | 朱应怀 宋礼成 |
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| 作者单位： | Department of Chemistry, Nankai University, Tianjin 300071, China |
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| 摘 要： | 尽管目前人们对富勒烯C60]的过渡金属有机物研究较多1],但通过氮卡宾方式连接的C60二茂铁衍生物尚未见报道。鉴于对C60反应的浓厚兴趣及二茂铁的广泛应用价值2]我们 利用C60的缺电子性3]将其与二茂铁甲基氮卡宾进行1+2]环加成反应,分离并表征了一种具有齿轮式结构的新奇C60二茂铁衍生物(CpFeC5H4CH2N)5C60(l)。
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| 关 键 词： | 富勒烯[C5H4CH2] 二茂铁甲基叠氮化物 环加成 |
Synthesis and Structure of a novel Fullerene[C60] derivative covalently linked to five ferrocenylmethylimino Substituents |
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| Ying-Huai Zhu,Li-Cheng Song.Synthesis and Structure of a novel Fullerene[C60] derivative covalently linked to five ferrocenylmethylimino Substituents[J].Chemical Research In Chinese Universities,1998,19(Z1):336. |
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| Authors: | Ying-Huai Zhu Li-Cheng Song |
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| Institution: | Department of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | The Synthesis of a fullereneC60] derivativeCpFeC5H4CH2N]5C60 is described, Spectroscopic evidence suggests its five CpFeC5H4CH2N moietes being bonded to five parallel6,6] bonds across the equatorical plane of fullereneC60]to give a gear-like structure. |
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| Keywords: | Fullerene[C60] Ferrocenylmethyl azide Cycloaddition |
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