| An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride |
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| 作者姓名： | Zhi Bin XU Zong Ru GUO |
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| 作者单位： | Zhi Bin XU，Zong Ru GUO* Institute of Materia Medica，Chinese Academy of Medical Sciences & Peking Union Medical College，Beijing 100050 |
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| 摘 要： | N-(2,4-Dinitrophenyl)-4-amino-n-butyl aldehyde 3 was obtained with high yield of 80% when N-(2,4-dinitrophenyl)-L-proline 1 reacted with SOCl2 at room temperature,However,the anticipated product N-(2,4-dinitrophenyl)-Tetrahydropyrrolyl-2-(4-methylthiophenyl)ketone 2 did not be produced.The mechanism was discussed in this article.
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| 关 键 词： | N-(2 4-二硝基苯)-L-脯氨基 亚硫酰(二)氯 FDNB 化学反应 反应机理 |
An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride |
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| Zhi Bin XU Zong Ru GUO.An Abnormal Reaction of N-(2,4-dinitrophenyl)-L-proline with Thionyl Chloride[J].Chinese Chemical Letters,2003,14(2):133-134. |
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| Authors: | Zhi Bin XU Zong Ru GUO |
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| Abstract: | N- (2,4-Dinitrophenyl)-4-amino-n-butyl aldehyde 3 was obtained with high yield of 80% when N- (2,4-dinitrophenyl)-L-proline 1 reacted with SOCl2 at room temperature. However, the anticipated product N- (2,4-dinitrophenyl)-tetrahydropyrrolyl-2- (4-methylthiophenyl) ketone 2 did not be produced. The mechanism was discussed in this article. |
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| Keywords: | L-Proline 1-fluoro-2 4-dinitrobenzene(FDNB) N-(2 4-dinitrophenyl)-4-amino-n-butyl aldehyde |
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