Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality |
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| Authors: | Branco Luís C Gois Pedro M P Lourenço Nuno M T Kurteva Vanya B Afonso Carlos A M |
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| Affiliation: | REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa, Quinta da Torre, 2829-516, Caparica, Portugal. |
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| Abstract: | ![]()
New chiral ionic liquids can be prepared simply by combining the tetra-n-hexyl-dimethylguanidinium cation with readily available chiral anions and used as an asymmetric inducing agent as demonstrated for catalytic Rh(II) carbenoid C-H insertion and Sharpless dihydroxylation. |
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