X-ray Crystal Structure of a Mononuclear Copper (Ⅱ) Complex with Unusual Monodentate O-coordination of Carboxylate Group of Isonicotinate 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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X-ray Crystal Structure of a Mononuclear Copper (Ⅱ) Complex with Unusual Monodentate O-coordination of Carboxylate Group of Isonicotinate

作者姓名：	Feng Mei NIE Yan Mei LI Yu Fen ZHAO

作者单位：	Feng Mei NIE; Yan Mei LI ; Yu Fen ZHAO ;(Bio-organic Phosphor-us Chemistry Laboratory Department of ChemistryTsinghua University，Beijing 100084

摘要：	Copperproteinsitesareassociatedwithavarietyofvitalbiologicalfunctions,includingelectrontransfer,anddioxygentransportandactivationl.ThelargemolecularweightandcomPlexnatureoftheproteinsmakedetailedstudiesoftheiractivesitesandchemistryverydifficult-Tobetterunderstandtheinherentcoordinationchemistryassociatedwiththeactivesite,syntheticanalogsaremostuseful2.Histidine(imidazole)playskeyrolesinthecatalyticfunctionsofalmostallofthemetalloenzymes.Therefore,complexeswithinddazoleligandsareofinterestast…
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