Methane activation by silica-supported Zr(IV) hydrides: the dihydride [(triple bond)SiO)2ZrH2] is much faster than the monohydride [(triple bond)SiO)3ZrH |
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| Authors: | Thieuleux Chloé Quadrelli Elsje Alessandra Basset Jean-Marie Döbler Jens Sauer Joachim |
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| Affiliation: | Laboratoire de Chimie Organometallique de Surface, UMR9986-CNRS CPE, 43 Boulevard du 11 Novembre 1918, F-69616 Villeurbanne, France. |
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| Abstract: | ![]()
The silica-supported Zr(iv) dihydride [(triple bond)SiO)2ZrH2] reacts quickly and completely with methane to yield [(triple bond)SiO)2ZrMe2] through the intermediate [(triple bond)SiO)2ZrHMe], while its monohydride analogue [(triple bond)SiO)3ZrH] yields the monomethylated product [(triple bond)SiO)3ZrMe] slowly and incompletely. |
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