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Copper Nanoflowers on Carbon Cloth as a Flexible Electrode Toward Both Enzymeless Electrocatalytic Glucose and H2O2
Authors:Kun Yuan  Yuchan Zhang  Shihao Huang  Shengfei Yang  Shuang Zhao  Fangxin Liu  Qianyu Peng  Yinping Zhao  Guangyuan Zhang  Jingchuan Fan  Guangchao Zang
Institution:1. Laboratory of Tissue and Cell Biology, Lab Teaching & Management Center, Chongqing Medical University, Chongqing, 400016 P.R. China

These authors contributed equally to this work.;2. Laboratory of Tissue and Cell Biology, Lab Teaching & Management Center, Chongqing Medical University, Chongqing, 400016 P.R. China;3. Laboratory of Tissue and Cell Biology, Lab Teaching & Management Center, Chongqing Medical University, Chongqing, 400016 P.R. China

Key Laboratory for Biorheological Science and Technology of Ministry of Education, State and Local Joint Engineering Laboratory for Vascular Implants, Bioengineering College of Chongqing University, Chongqing, 400030 China

Abstract:Herein, a novel electrochemical sensor for glucose and hydrogen peroxide (H2O2) detection was successfully developed through the use of Cu nanoflowers (CuNFs) combined with flexible carbon cloth (CC) substrate. The 3D flower-like CuNFs in size uniformly and firmly grow on CC substrate by a facile, scalable, one-step hydrothermal strategy. Morphology, size and surface property of the prepared CuNFs/CC were examined by SEM, EDS and TEM, respectively. The electrochemical mechanism of CuNFs/CC for glucose and H2O2 detection was investigated by cyclic voltammetry. High electrochemical performances were displayed with amperometric i-t curves including a wide linear range from 1.0 nM to 6.0 mM for glucose and from 1.0 μM to 36.66 mM for H2O2, respectively. Good sensitivity, repeatability, and stability, as well as anti-interference ability, the carbon cloth-supported CuNFs will be the promising materials for fabricating practical non-enzymatic glucose and H2O2 sensors.
Keywords:Glucose  hydrogen peroxide  electrooxidation  electroreduction  nonenzymatic sensor  
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