Unusually facile transformations of cyclopentane into cyclohexanes, decalins, and adamantanes |
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| Authors: | I S Akhrem S V Vitt I M Churilova A V Orlinkov |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Cyclopentane is converted into a mixture of cyclohexanes, decalins, and adamantanes (and isomeric cycloalkanes) in overall
yields of 18–31% (w/w) under the action of superelectrophilic complex CBr4·2AlBr3 either in CH2X2 (X=Br, Cl) or without a solvent at 20°C.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2304–2309, December, 1999. |
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| Keywords: | cyclopentane cyclohexanes decalins adamantanes tricyclanes superelectrophilic complex CBr4·2AlBr3 cyclooligomerization GLC-MS analysis |
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