| μ-氧-双[三(邻溴苄基)锡]的合成和结构研究 |
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| 引用本文： | 张复兴,王剑秋,邝代治,冯泳兰,许志锋.μ-氧-双[三(邻溴苄基)锡]的合成和结构研究[J].无机化学学报,2004,20(2):202-204. |
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| 作者姓名： | 张复兴 王剑秋 邝代治 冯泳兰 许志锋 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省自然科学基金资助项目(No.00JJY2010,02JJY3005)，湖南省教育厅资助项目(No.02C135,02C137)。 |
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| 摘 要： | The tri(o-bromobenzyl)tin bromide was treated with aqueous solution of NaOH to formed the μ-oxygen-bistri(o-bromobenzyl)tin]. The crystal structures of compound was determined by X-ray diffraction. The crystal belongs to triclinic, space group with a=1.0544(4) nm, b=1.1029 (4) nm, c=1.1309 (4) nm, α =117.031(5) °, β=107.685 (6) °, γ=98.523(6) °, V=1.0506(6)nm3, Z=1, Dx=2.013g·cm-3, μ(MoKα)=69.25cm-1, F(000)=606, R1=0.0524, wR2=0.1196. In the struture the tin atom has a distorted tetrahedral geometry. CCDC: 220514.
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| 关 键 词： | μ-氧-双[三(邻溴苄基)锡] 合成 晶体结构 |
| 修稿时间： | 2003年8月20日 |
Study on Synthesis and Crystal Structure of the μ-oxygen-bis[tri(o-bromobenzyl)tin] |
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| ZHANG Fu-Xing,WANG Jian-Qiu,KUANG Dai-Zhi,FENG Yong-Lan and XU Zhi-Feng.Study on Synthesis and Crystal Structure of the μ-oxygen-bis[tri(o-bromobenzyl)tin][J].Chinese Journal of Inorganic Chemistry,2004,20(2):202-204. |
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| Authors: | ZHANG Fu-Xing WANG Jian-Qiu KUANG Dai-Zhi FENG Yong-Lan and XU Zhi-Feng |
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| Institution: | Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008 and Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008 |
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| Abstract: | |
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| Keywords: | oxygen-bis[tri(o-bromobenzyl)abstract:tin] synthesis crystal structure |
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