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| 对巯基苯甲酸在电化学沉积金膜表面的SERS研究 | |
| 引用本文： | 马文强,荆翠玉,郝刚领. 对巯基苯甲酸在电化学沉积金膜表面的SERS研究[J]. 光散射学报, 2010, 22(1): 39-43 |
| 作者姓名： | 马文强 荆翠玉 郝刚领 |
| 作者单位： | 1. 物理与电子信息学院延安大学,延安,716000;首都师范大学北京市纳米光电子学重点实验室,北京,100037 2. 首都师范大学北京市纳米光电子学重点实验室,北京,100037 3. 物理与电子信息学院延安大学,延安,716000 |
| 基金项目： | 陕西省科技厅资助项目(SJ08-ZJ05) |
| 摘 要： | SERS技术由于具有高灵敏度的表面效应,能够检测吸附在金属表面的单分子层或亚单分子层的分子,并能给出丰富的分子结构信息,因而己被广泛应用于界面科学以及定性和定量分析科学领域之中。本文在制备电化学沉积金纳米薄膜的基础上,利用扫描电镜观察金纳米薄膜的形貌,通过分析对巯基苯甲酸在电化学沉积金膜表面的SERS光谱,研究对巯基苯甲酸在金纳米薄膜表面的吸附方式。由SERS光谱分析,我们推断出对巯基苯甲酸可能通过羧基和S原子共同作用吸附在金纳米颗粒表面,且苯环平面可能与金薄膜表面成一定倾斜角。 |
| 关 键 词： | 表面增强拉曼散射 电化学沉积 吸附方式 |
| 收稿时间： | 2009-09-15 |
The Studies on the SERS Spectra of 4-Mercaptobenzoic Acid Adsorbed on Gold Film by Electrochemical Deposition |
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| MA Wen-qiang,JING Cui-Yu,HAO Gang-ling. The Studies on the SERS Spectra of 4-Mercaptobenzoic Acid Adsorbed on Gold Film by Electrochemical Deposition[J]. Chinese Journal of Light Scattering, 2010, 22(1): 39-43 | |
| Authors: | MA Wen-qiang JING Cui-Yu HAO Gang-ling |
| Affiliation: | 1.Department of Physical and Electronic Information;Yanan University;Yanan of Shanxi Province;Yanan 761000;China;2.Beijing Key Lab for Nano-photonics and Nano-structure;Department of Physics;Capital Normal University;Beijing 100037;China |
| Abstract: | Since the first observation of surface-enhanced Raman scattering(SERS),this technology,with its very high surface sensitivity and selectivity,has emerged as a routine and powerful tool for the investigation and structural characterization of interfaces and thin-film solid materials.This paper reports that a new SERS-active gold film on the surfaces of a series of electric material has been prepared by an electrochemical technique in an aqueous solution of KAuCl4.With scanning electron microscopy,the morphol... |
| Keywords: | surface-enhanced Raman scattering(SERS) electrochemical deposition adsorption behavior |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |