| RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST |
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| 作者姓名： | Yi-jun Huang Guo-rong Qi Guan-xi Chen |
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| 作者单位： | Yi-jun Huang;Guo-rong Qi;Guan-xi Chen Department of Polymer Science and Engineering，Zhejiang University;Hangzhou 310027，China |
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| 摘 要： | Copolymerization of propylene oxide (PO) and ethylene oxide (EO) using double metal cyanide (DMC) complexas the catalyst was carried out. The structure of random copolymers was confirmed by ~(13)C-NMR and IR spectra. ~1H-NMRanalysis shows that the EO content in the copolymer is the same as that in the initial monomer feed. Moderate molecularweight copolymers with various EO content were obtained and their values of molecular weigh distribution (MWD) fell inthe range of 1.21-1.55. It was found that the molecular weight of copolymers is controlled by the mass ratio of EO + PO toinitiator moles used. The reaction rate as well as polymer yield decrease with increasing EO content in the feed composition.
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| 收稿时间： | 2001-11-29 |
| 修稿时间： | 2001-12-25 |
RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST |
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| Yi-jun Huang,Guo-rong Qi,Guan-xi Chen.RANDOM COPOLYMER OF PROPYLENE OXIDE AND ETHYLENE OXIDE PREPARED BY DOUBLE METAL CYANIDE COMPLEX CATALYST[J].Chinese Journal of Polymer Science,2002,0(5):453-459. |
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| Authors: | Yi-jun Huang Guo-rong Qi Guan-xi Chen |
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| Institution: | Department of Polymer Science and Engineering; Zhejiang University; Hangzhou 310027; China |
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| Abstract: | Copolymerization of propylene oxide (PO) and ethylene oxide (EO) using double metal cyanide (DMC) complexas the catalyst was carried out. The structure of random copolymers was confirmed by ~(13)C-NMR and IR spectra. ~1H-NMRanalysis shows that the EO content in the copolymer is the same as that in the initial monomer feed. Moderate molecularweight copolymers with various EO content were obtained and their values of molecular weigh distribution (MWD) fell inthe range of 1.21-1.55. It was found that the molecular weight of copolymers is controlled by the mass ratio of EO + PO toinitiator moles used. The reaction rate as well as polymer yield decrease with increasing EO content in the feed composition. |
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| Keywords: | Propylene oxide Ethylene oxide Double metal cyanide complex |
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