Regioselective metathesis reactions of various polyunsaturated ketones and alcohols |
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| Authors: | Chahinez Aouf Nicolas Galy Henri Doucet Maurice Santelli |
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| Affiliation: | 1. Laboratoire Chimie Provence, associé au CNRS no. 6264, Université d'Aix‐Marseille, Avenue Escadrille Normandie‐Niemen, 13397 Marseille Cedex 20, France;2. Institut Sciences Chimique de Rennes, UMR 6226 ‘Catalyse et Organométalliques’, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes, France |
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| Abstract: | The reactivity for metathesis reaction of some polyunsaturated cyclopentanols, and of a polyunsaturated ketone bearing vinyl groups or vinyl and propenyl groups has been examined. In the presence of two of these reactants, depending on the ruthenium catalyst employed, either the ring closing metathesis or the cross‐coupling metathesis was observed. Copyright © 2010 John Wiley & Sons, Ltd. |
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| Keywords: | metathesis lactones indenols cyclization |
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