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Novel methodologies for the synthesis of functionalized lipophilic carboranes |
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| Authors: | Subash C Jonnalagadda Steven R Verga Parth D Patel A V Reddy T Srinivas Patricia M Scott Venkatram R Mereddy |
| Institution: | 1. Department of Chemistry and Biochemistry, Rowan University, Glassboro, NJ USA;2. Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, MN USA |
| Abstract: | Novel synthetic protocols for the synthesis of lipophilic carboranes were developed utilizing two C? C bond forming reactions, namely Baylis–Hillman and enynedioate cycloaddition reactions. Some of these carboranes were converted into further functionalized carboranes via nucleophilic allylic isomerization. Copyright © 2009 John Wiley & Sons, Ltd. |
| Keywords: | carboranes low density lipoprotein lipophilic carboranes cholesterol Baylis Hillman reaction |