Generation of chromioenamines by reduction of O-acetyloximes with chromium(II) and their application |
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| Authors: | Takai K Katsura N Kunisada Y |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, Okayama 700-8530, Japan. ktakai@cc.okayama-u.ac.jp |
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| Abstract: | Chromioenamines can be generated by treatment of O-acetyloximes with chromium(II) via two steps of one-electron reduction and successive isomerization, and the species react with aldehydes to give gamma-amino alcohols after reduction with LiAlH4. |
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