Indium-catalyzed construction of polycyclic aromatic hydrocarbon skeletons via dehydration |
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| Authors: | Kuninobu Yoichiro Tatsuzaki Tomohiro Matsuki Takashi Takai Kazuhiko |
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| Institution: | Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp |
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| Abstract: | Polycyclic aromatic compounds can be synthesized from 2-benzylic- or 2-allylbenzaldehydes using a catalytic amount of In(III) or Re(I) complexes. By using this method, polycyclic aza-aromatic compounds can also be prepared efficiently. In these reactions, only water is formed as a side product. |
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