New approach for consideration of adsorption/desorption data |
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| Institution: | 1. Faculty of Physics, University of Bucharest, P.O. Box MG-7, Măgurele 077125, Romania;2. Mihail Sadoveanu Theoretical High School, District 2, Bucharest 021586, Romania;3. Kazan (Volga Region) Federal University, Kazan 420008, Tatarstan, Russia;4. Izmir Institute of Technology, Faculty of Science, Izmir TR-35430, Turkey;5. Advanced Technologies Research & Application Center, Mersin University, TR-33343 Yenisehir, Mersin, Turkey;1. Electrochemistry Research Group, Department of Applied Science, Dundalk Institute of Technology, Dublin Road Dundalk, County Louth, Ireland;2. Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS University Islamabad, Lahore Campus, Pakistan;3. School of Chemical Sciences, Dublin City University, Glasnevin, Dublin 9, Ireland;4. Materials and Surface Science Institute, University of Limerick, Limerick, Ireland;5. Department of Physics, Chemistry and Biology, Linköping University, SE-581 83, Linköping, Sweden;6. Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, SE-601 74, Norrköping, Sweden;1. College of Engineering, Bohai Unibersity, Jinzhou, 121013, China;2. College of New Energy, Bohai Unibersity, Jinzhou, 121013, China;1. Siemens AG, Corporate Technology, Munich, Germany;2. Max Planck Institute for Solid State Research, Stuttgart, Germany;3. Chemistry Department, Ludwig Maximilian University, Munich, Germany;1. Instituto de Tecnología Química CSIC-UPV, Universitat Politécnica de Valencia, Av. De los Naranjos, 46022 Valencia, Spain;2. INCDTIM Cluj-Napoca, Str. Donat nr. 67-103, PO 5 Box 700, 400293 Cluj-Napoca, Romania;3. Department of Organic Chemistry, Biochemistry and Catalysis, University of Bucharest, B-dul Republicii 4-12, Bucharest 030016, Romania |
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| Abstract: | In this paper we proposed a new approach to modify the Langmuir model by considering nonlinear effects such as diffusion of water molecules in/out of an adsorbing film for humidity adsorption and desorption kinetics. The model was tested on the humidity adsorption and desorption data of a spin coated 50 nm thick Ruthenium polypridyl complex (Ru-PC K314) film, measured under relative humidity between 11% and 97% using by Quartz Crystal Microbalance (QCM) technique. |
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