Synthesis of ultrahigh-pore-volume carbon aerogels through a “reinforced-concrete” modified sol-gel process |
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Authors: | Qingjun Chen Liang Chen |
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Institution: | State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China |
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Abstract: | Ultrahigh-pore-volume carbon aerogels were synthesized by adding rigid silica nanoparticles to resorcinol-formaldehyde sols, followed by supercritical drying, pyrolysis and HF leaching. The presence of silica nanoparticles in polymer gels dramatically inhibits volume shrinkage and framework collapse during the supercritical drying and pyrolysis processes, resulting in the obtained carbon aerogels exhibiting very low bulk density and high pore volume. By changing the mass ratio of silica nanoparticles/resorcinol-formaldehyde resin, pore volumes of carbon aerogels can be tuned in the range of 2.8-6.0 cm3/g. |
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Keywords: | Carbon aerogels Sol-gel preparation Silica nanoparticles Porosity |
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