| 乙烯渣油沥青基活性炭纤维和粘胶基活性炭纤维的表面性质与脱硫活性 |
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| 引用本文： | 李开喜,凌立成,刘朗,张碧江,刘振宇.乙烯渣油沥青基活性炭纤维和粘胶基活性炭纤维的表面性质与脱硫活性[J].化学物理学报(中文版),2000,13(2):231-237. |
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| 作者姓名： | 李开喜 凌立成 刘朗 张碧江 刘振宇 |
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| 作者单位： | 中国科学院山西煤炭化学研究所,煤转化国家重点实验室,太原,030001
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| 基金项目： | 中国科学院资助项目，教育部留学回国人员科研启动基金 |
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| 摘 要： | 研究了在O2和H2O存在下,乙烯渣油沥青基活性炭纤维(ETPACF)和粘胶基活性炭纤维(CelluloseACF)的脱硫活性.结果表明,在比表面积相近的情况下,ETPACF的脱硫活性明显低于CelluloseACF,这可归因于后者具有较强的吸附和催化氧化SO2能力及较大的吸水量,尤其是具有较强的催化氧化SO2的能力,这些能力又与其表面含有含氮官能团以及某些含氧官能团有关,因此ACF的表面官能团对其脱硫活性影响很大.
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| 关 键 词： | 活性炭纤维 SO2脱除 催化活性 |
The Activities of Activated Carbon Fibers from Ethylene Tar Pitch and Cellulose |
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| Li Kaixi,Ling Licheng,Liu Lang,Zhang Bijiang,Liu Zhenyu.The Activities of Activated Carbon Fibers from Ethylene Tar Pitch and Cellulose[J].化学物理学报(中文版),2000,13(2):231-237. |
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| Authors: | Li Kaixi Ling Licheng Liu Lang Zhang Bijiang Liu Zhenyu |
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| Abstract: | The activities of activated carbon fibers(ACFs) from ethylene tar pitch (ETP) and cellulose were examined for the oxidative conversion of SO2 into aq. H2SO4 in the presence of O2 and H2O. The results indicated that Cellulose ACF showed much higher activity than ETP ACF, owning to higher ability of SO2 adsorption, higher catalytic activity for the oxidation of SO2 to SO3 and larger amount of H2O adsorption, enhanced catalytic activity for the oxidation of SO2 to SO3 showed highest among these abilities. These in turn depend on nitrogencontaining group and some oxygen-containing group in the surface of cellulose ACF, so the SO2 removal activity of ACFs is affected by functional groups. |
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| Keywords: | Activated carbon fibers SO2 removal Catalytic properties |
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