Synthesis, Structure and Photoluminescence of One Zinc-based Metal-metallosalen Framework |
| |
Authors: | ZHU Cheng-Feng BAN Feng-Jun SHENG En-Hong ZHENG Sai-Jing LIU Bai-Zhan CUI Yong |
| |
Institution: | 1. School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China 2. China Tobacco, Shanghai 200240, China 3. College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China;China Tobacco, Shanghai 200240, China |
| |
Abstract: | Dicarboxyl-functionalized salen ligand 1,2-phenylendiamine-N,N?-bis(3-tert-butyl- 5- (carboxyl)-salicylide-ene (H_4L) was synthesized in good yield from 3-tert-butyl-5-formyl-4-hy- droxybenzoic acid and used to construct a 2D zinc complex, (ZnL)Zn3/2(BDC)1/2(DMSO)2]?3DMSO (ZnL)Zn_(3/2)(BDC)_(1/2)(DMSO)_2]·3DMSO (1, BDC = 1,4-benzenedicarboxylate), under mild reaction conditions. 1 was characterized by IR, microanalysis, TGA and single-crystal X-ray crystallography. It crystallizes in triclinic space group P_1~- with a = 11.3860(4), b = 13.2636(5), c = 17.5503(7) , α = 92.2240(10), β = 94.5070(10), γ = 96.0580(10)°, V = 2624.52(17) ~3, Z = 2, M_r = 1143.62, D_c = 1.448 g/cm3, F(000) = 1186, μ = 1.395 mm~(-1), GOOF = 0.993, the final R = 0.0380 and wR = 0.1280 for 21752 observed reflections with I > 2σ(I). The 2D coordination polymer 1 is further assembled into a 3D supramolecular network structure via π…π interactions between the aromatic rings of the ligands in adjacent layers. Thermal gravimetric analysis demonstrates that 1 is a thermally robust structure with network decomposition temperatures of 420 ℃ and it also exhibits strong photoluminescence in the visible region. |
| |
Keywords: | crystal structure salen coordination polymer photoluminescence thermal properties |
本文献已被 万方数据 等数据库收录! |
|