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Effect of medium on the rate constant of decomposition of di(tert-butyl)trioxide
Authors:A. F. Khalizov  S. L. Khursan  V. V. Shereshovets
Affiliation:(1) Institute of Organic Chemistry, Ufa Scientific Center of Ural Branch of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation
Abstract:
It was found that the medium affects the rate constant of the thermal decomposition of di(tert-butyl)trioxide. In all solvents studied, the decomposition occurred according to the first-order law. The effect of the solvent on the rate constant was analyzed within the framework of the Koppel-Palm equation.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1167–1168, June, 1995.The authors are grateful to O. N. Makarova for help in this work.This study was financially supported by the Russian Foundation for Basic Research (Grant No. 93-03-5231).
Keywords:trioxide  chemiluminescence  decomposition mechanism.
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