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N-亚水杨基苄胺过渡金属配合物的合成、结构与抑菌性能研究(英)
引用本文:许兴友,高健,陈军,李善忠,杨绪杰,李一志,刘永江.N-亚水杨基苄胺过渡金属配合物的合成、结构与抑菌性能研究(英)[J].无机化学学报,2005,21(5):767-770.
作者姓名:许兴友  高健  陈军  李善忠  杨绪杰  李一志  刘永江
作者单位:1. 淮海工学院化学工程系,连云港,222005;南京理工大学材料化学实验室,南京,210094
2. 南京理工大学材料化学实验室,南京,210094
3. 淮海工学院化学工程系,连云港,222005;南京大学配位化学国家重点实验室,南京,210093
4. 南京大学配位化学国家重点实验室,南京,210093
基金项目:江苏省海洋生物技术重点建设实验室资助。
摘    要:N-salicylidene-benzylamineato M(Ⅱ) complexes (ZnL2, CuL2 and CdL2) were synthesized, characterized and valued for antimicrobial activities against bacterial strands using the agar diffusion method. The crystal of ZnL2 was determined by X-ray diffraction. It crystallizes in the Monoclinic system, space group C2/c with a=2.269 1(3), b=0.918 2(1), c=1.239 5(2) nm, β=117.89(2), Z=4, R1=0.049 4, wR2=0.138 2. The complexes were found to be active against Staphylococcus aureus and Eschierichia Coli. CCDC: 249474.

关 键 词:N-亚水杨基苄胺配合物    合成    晶体结构    抑菌性
收稿时间:2004/10/10 0:00:00
修稿时间:2004/12/31 0:00:00

Synthesis, Structure and Antimicrobial Study of N-salicylidene-benzylamineato Transition Metal Complexes
XU Xing-You,GAO Jian,CHEN Jun,LI Shan-Zhong,YANG Xu-Jie,LI Yi-Zhi and LIU Yong-Jiang.Synthesis, Structure and Antimicrobial Study of N-salicylidene-benzylamineato Transition Metal Complexes[J].Chinese Journal of Inorganic Chemistry,2005,21(5):767-770.
Authors:XU Xing-You  GAO Jian  CHEN Jun  LI Shan-Zhong  YANG Xu-Jie  LI Yi-Zhi and LIU Yong-Jiang
Institution:Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005; Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005; State Key Laboratory of Coordination, Coordination Chemistry Institute, Nanjing University, Nanjing 210093,Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005; Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,State Key Laboratory of Coordination, Coordination Chemistry Institute, Nanjing University, Nanjing 210093 and State Key Laboratory of Coordination, Coordination Chemistry Institute, Nanjing University, Nanjing 210093
Abstract:N-salicylidene-benzylamineato M(Ⅱ) complexes (ZnL2, CuL2 and CdL2) were synthesized, characterized and valued for antimicrobial activities against bacterial strands using the agar diffusion method. The crystal of ZnL2 was determined by X-ray diffraction. It crystallizes in the Monoclinic system, space group C2/c with a=2.2691 (3), b =0.918 2(1), c = 1.239 5 (2) nm,β= 117.89(2), Z=4, R1=0.049 4, wR2=0.138 2. The complexes were found to be active against Staphylococcus aureus and Eschierichia Coli. CCDC: 249474.
Keywords:N-salicylidene-benzylamineato  M(Ⅱ) complex  synthesis  crystal structure  antimicrobial activity
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