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Synthesis of substituted 1,3-thiazinoazoles
Authors:N D Abramova  L V Andriyankova  Yu M Skvortsov  A G Mal'kina  é I Kositsyna  A I Albanov  G G Skvortsova
Institution:(1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033 Irkutsk
Abstract:Substituted 1,3-thiazinoazoles were obtained by treating benzimidazole-2-thione, 4,5-diphenylimidazole-2-thione, and 1,2,4-triazole-3-thione with tertiary cyanoacetylenic alcohols and their acetals in the presence of lithium hydroxide. Treatment of the 1,3-thiazinobenzimidazoles with base destroyed the thiazino ring forming benzimidazol-2-one.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1412–1415, October, 1986.
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