Synthesis,Structure,and Magnetic Property of One Novel Entangled Cobalt~Ⅱ-organic Compound |
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引用本文: | 张梁栋,范黎明,刘光增,魏培海,李斌,张修堂.Synthesis,Structure,and Magnetic Property of One Novel Entangled Cobalt~Ⅱ-organic Compound[J].结构化学,2011,30(7). |
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作者姓名: | 张梁栋 范黎明 刘光增 魏培海 李斌 张修堂 |
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作者单位: | Advanced Material Institute of Research;Department of Chemistry;Qilu Normal University;College of Chemistry and Chemical Engineering;Jinan University;Liaocheng University; |
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基金项目: | supported by the National Natural Science Foundation of China (20873163); the Natural Science Foundation of Shandong Province (BR2010BQ023); Shandong Provincial Education Department (J09LB55); Qilu Normal University |
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摘 要: | One novel entangled cobalt compound,{Co 3 (nbta) 2 (4,4-bpy) 2 (H 2 O) 2 ](H 2 O) 2 } n (1,H 3 nbta=5-nitro-1,2,3-benzenetricarboxylic acid,4,4-bpy=4,4-bipyridyl),was prepared and characterized by X-ray diffraction,magnetism,elemental analysis,XPS,TGA and IR spectroscopy.The crystal of 1 crystallizes in monoclinic,space group Pc with a=13.0717(16),b=11.4167(14),c=15.9342(19),β=90.5190(10)o,V=2377.9(5)3,Z=2,C 48 H 36 Co 3 N 8 O 20,M r=1221.64,D c=1.706 g/cm 3,F(000)=1242 and μ(MoKα)=1.128 mm-1.The final R=0.0497 and wR=0.1461 for 4185 observed reflections with I > 2σ(I) and R=0.0721 and wR=0.1619 for all data.X-ray diffraction analyses revealed that Co(1) is linked by the nbta 3-ligands to form the ladder shape along the c axis,which is further extended into two-dimensional networks via the joint of Co(2) along the a axis.Moreover,these two dimensional motifs are interconnected by the 4,4-bpy bridges to form a complicated 3-D polymeric framework.Magnetic measurements revealed that compound 1 shows strong antiferromagnetic property.
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关 键 词: | 5-nitro-1 2 3-benzenetricarboxylic acid 4 4'-bipyridyl cobalt(Ⅱ) XPS antiferromagnetic |
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