Thermodynamic regularities for associating fluids from statistical associating fluid theory equation of state |
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Authors: | A. Maghari Z. Safaei |
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Affiliation: | 1. Department of Physical Chemistry, University College of Science, University of Tehran, Tehran, Iran
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Abstract: | In this work, we used a statistical associating fluid theory to analyze two important thermodynamic regularities for some associating fluids, including water, methanol and ethanol. The studied regularities included: (i) the common bulk modulus point on the isotherms of the reduced bulk modulus versus reduced density, (ii) near linearity of the reduced isothermal bulk modulus as a function of reduced pressure. In this work, we also reported the influence of the molecular size and interaction strength on the bulk modulus point. |
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