Syntheses and applications of C2-symmetric chiral diols |
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| Affiliation: | 3. Chemical Engineering and Process Development Division, CSIR-National Chemical Laboratory, Pune-411008;4. Academy of Scientific and Innovative Research (AcSIR), CSIR-NCL Campus, Pune-411008;5. CSIR-Institute of Genomics and Integrative Biology, New Delhi 110020, India;1. Department of Chemistry, Goa University, Taleigao Plateau, Goa 403206, India;2. Organic Chemistry Department, RUDN University, 6 Miklukcho-Maklaya Str., Moscow 117198, Russian Federation |
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| Abstract: | Synthetic procedures for a large variety of C2-symmetric chiral diols are reviewed. Prominent among these procedures are enantioselective reductions, epoxide-cleavages, dihydroxylation of olefins, and synthetic transformations. Applications of these diols as chiral auxiliaries/ligands for several important reactions are also highlighted. |
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