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Stereocontrolled synthesis of the DE ring system of the marine alkaloid upenamide |
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| Authors: | Kiewel Kurt Luo Zhushou Sulikowski Gary A |
| Institution: | Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. |
| Abstract: | reaction: see text] A stereocontrolled synthesis of the DE fragment (2) of the marine alkaloid upenamide (1) is described. The synthesis proceeds in 12 steps from caprolactone (10) and 20-25% overall yield. |
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