Kerr constants and dipole moments of aminobenzoic acids in dioxane |
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Authors: | Yu G Kondrashina S G Vul'fson A P Timosheva |
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Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan ' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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Abstract: | Aminobenzoic acids in dioxane have been investigated by dipole moment and Kerr effect methods.m-Aminobenzoic acid exists in a solution mainly (60 %) in thesyn-form. Inp-aminobenzoic acid, conjugation flattens the pyramidal configuration of the nitrogen atom, which is even more flattened ino-aminobenzoic acid owing to an intramolecular hydrogen bond.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 859–861, May, 1994. |
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Keywords: | aminobenzoic acids structure Kerr constants dipole moment polarizability interaction moment |
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