| A Short and Stereoselective Synthesis of the （-）-（5R, 6S）-6-Acetoxy-hexadecane-5-olide |
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| 作者姓名： | BinSUN LiZengPENG XueSongCHEN YuLinLI YingLI |
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| 作者单位： | [1]StateKeyLaboratoryofAppliedOrganicChemistry,InstituteofOrganicChemistry,LanzhouUniversity,Lanzhou730000 [2]LunanPharmaceuticalCo.Ltd.,Linyi276003 |
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| 摘 要： | (-)-(5R, 6S)-6-Acetoxyhexadecan-5-olide 1, a natural mosquito attractant pheromone,was synthesized from readily available aldehyde 2 and cyclopentanone 3 using L-proline-catalyzed asymmetric aldol reaction as the key step.
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| 关 键 词： | 立体选择性合成 （-）-（5R 6S）-6-乙酰氧基十六烷-5-交酯 2羟基丁醛反应 L-脯氨酸 不对称反应 |
A Short and Stereoselective Synthesis of the (-)-(5R, 6S)-6-Acetoxy hexadecane-5-olide |
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| BinSUN LiZengPENG XueSongCHEN YuLinLI YingLI.A Short and Stereoselective Synthesis of the (-)-(5R, 6S)-6-Acetoxy hexadecane-5-olide[J].Chinese Chemical Letters,2004,15(10):1177-1178. |
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| Authors: | Bin SUN Li Zeng PENG Xue Song CHEN Yu Lin LI Ying LI State Key Laboratory of Applied Organic Chemistry |
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| Institution: | Bin SUN1,Li Zeng PENG2,Xue Song CHEN1,Yu Lin LI1,Ying LI1* 1 State Key Laboratory of Applied Organic Chemistry,Institute of Organic Chemistry,Lanzhou University,Lanzhou 730000 2Lunan Pharmaceutical Co.Ltd.,Linyi 276003 |
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| Abstract: | R, 6S)-6-Acetoxyhexadecan-5-olide 1, a natural mosquito attractant pheromone, was synthesized from readily available aldehyde 2 and cyclopentanone 3 using L-proline-catalyzed asymmetric aldol reaction as the key step. |
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| Keywords: | Acetoxyhexadecan-5-olide Baeyer-Villiger oxidation aldol reaction L-proline |
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