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Production of CO by UV irradiation of acetylacetone
Affiliation:1. Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China;2. Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy, Jilin University, Changchun 130012, China
Abstract:Photochemistry of hexafluoroacetylacetone has been studied by photoproduct analysis using infrared spectroscopy. Hexafluoroacetylacetone was irradiated by KrF excimer laser with the oscillation wavelength of 248 nm during 100 s and the photoproducts were analyzed by transmittance measurement of FT-IR in the spectral region between 3500 and 1300 cm−1. One of the photoproducts was CO. It was estimated that the formation efficiency of CO was approximately 0.6.
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