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Radiolysis of ferrocyanide solutions studied by infrared spectroscopy |
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| Affiliation: | 1. Institute of Technology for Nanostructures (NST) and Center for Nanointegration Duisburg-Essen (CENIDE), University Duisburg-Essen, Duisburg D-47057, Germany;2. Department of Information Technology, Quaid-e-Awam University of Engineering Science & Technology, Nawabshah, Sindh 67480, Pakistan |
| Abstract: | The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion. |
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