| 15-羟基十五烷酸的脂肪酶催化合成环十五内酯 |
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| 引用本文： | 潘湘波,梁静娟,刘雄民,熊德元,李飘英. 15-羟基十五烷酸的脂肪酶催化合成环十五内酯[J]. 应用化学, 2004, 21(8): 850-0 |
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| 作者姓名： | 潘湘波 梁静娟 刘雄民 熊德元 李飘英 |
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| 作者单位： | 广西大学 |
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| 基金项目： | 教育部科学技术重点项目资助 ( 2 0 4110 )，广西自然科学基金资助项目 (桂科自 0 13 5 0 13 ) |
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| 摘 要： | 15-羟基十五烷酸的脂肪酶催化合成环十五内酯
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| 关 键 词： | 15-羟基十五烷酸的脂肪酶催化合成环十五内酯 |
| 文章编号： | 1000-0518(2004)08-0850-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2003-08-29 |
Lipase Catalyzed Synthesis of Pentadecanolide from 15-Hydroxypentadecanoic Acid |
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| PAN Xiang-Bo,LIANG Jing-Juan,LIU Xiong-Min ,XIONG De-Yuan,LI Piao-Ying. Lipase Catalyzed Synthesis of Pentadecanolide from 15-Hydroxypentadecanoic Acid[J]. Chinese Journal of Applied Chemistry, 2004, 21(8): 850-0 |
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| Authors: | PAN Xiang-Bo LIANG Jing-Juan LIU Xiong-Min XIONG De-Yuan LI Piao-Ying |
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| Affiliation: | PAN Xiang-Bo,LIANG Jing-Juan,LIU Xiong-Min *,XIONG De-Yuan,LI Piao-Ying |
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| Abstract: | The pentadecanolide was biosynthesized in cyclohexane from 15-hydroxypentadecanoic acid, which as prepared from 15-tetracosenoic acid in Malania Olcifera Chum oil using lipase as catalyst. The effect of lipase activity on the lactonization was investigated. Lipases from fiften strains (13 strains of Candida and 2 strains of Penicillium) showed different catalytic effects to the synthesis reactions. The lipases from strains of Penicillium sp. and 4 strains of Candida sp. have catalytic lactonization activity, and the conversion ratio of substrate reached 88% by using lipase Candida sp.GXU01. |
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| Keywords: | cyclopentadecanolide lipase hydroxypentadecanoic acid |
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