FT-far-infrared spectroscopic studies of solute-solvent interactions and molecular dynamics in solutions of methanol,N-methyl formamide and N,N-dimethyl formamide期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

FT-far-infrared spectroscopic studies of solute-solvent interactions and molecular dynamics in solutions of methanol,N-methyl formamide and N,N-dimethyl formamide

Authors:	Richard Buchner Jack Yarwood

Affiliation:	(1) Department of Chemistry, University of Regensburg, D-8400 Regensburg, Germany;(2) Department of Chemistry, University of Durham, South Road, DH1 3LE Durham, UK

Abstract:	Quantitative measurements of the optical constants (4–170 cm^–1) of three organic liquids and their dilute solutions in carbon tetrachloride have been interpreted in terms of molecular relaxation processes arising from solute-solute and solute-solvent interactions. The behaviour of CH₃OH and NMF on dilution is quite different from that of DMF, emphasizing the importance of hydrogen bonding potentials in the former two liquids.

Keywords:	far-infrared dynamics liquids interactions
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