Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores |
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| Authors: | Horcajada Patricia Surblé Suzy Serre Christian Hong Do-Young Seo You-Kyong Chang Jong-San Grenèche Jean-Marc Margiolaki Irene Férey Gérard |
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| Affiliation: | Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035, Versailles Cédex, France. |
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| Abstract: | ![]()
The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe). |
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