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Syntheses of 3,7-dimethylpentadecan-2-ols from intermediates formed from co-oligomerisation reactions of butadiene with diethyl malonate and acetaldehyde
Authors:Raymond Baker  Peter M. Winton  Ralph W. Turner
Affiliation:Department of Chemistry, The University, Southampton, S09 5NH U.K.;ICI Ltd., Mereside, Alderley Park, Macclesfield, Cheshire, SK10 4TG. U.K.
Abstract:The products of the reaction of butadiene with diethyl malonate catalysed by a palladium complex and of butadiene with acetaldehyde catalysed by a nickel(0) complex have been used in two syntheses of 3,7-dimethylpentadecan-2-ol.
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