Enantioselectively catalyzed oxidation of 3,4-dihydroxy-l-phenylalanine by N-lauroyl L or D-histidine-Cu(II) complex in CTABr micelles. |
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| Authors: | Kimiho Yamada Hideto Shosenji Yonejiro Otsubo Shuji Ono |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kumamoto University, Kumamoto 860, Japan |
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| Abstract: | In order to investigate the enzyme model reaction the oxidation of 3,4-dihydihydroxy-L-phenylalanine(L-DOPA) was carried out using optically active catalyst, N-lauroyl L or D-histidine-Cu(II) complex(L or D-LauHis-Cu(II)), showing appreciable enantioselectivity in the presence of the mixed micelles with CTABr. |
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