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The visible absorption spectrum of S2O
Affiliation:1. Laboratory of Quantum Mechanics of Molecules and Radiative Processes, Tomsk State University 36, Lenin Ave., Tomsk 634050, Russia;2. Laboratory of Theoretical Spectroscopy, V.E. Zuev Institute of Atmospheric Optics SB RAS 1, Akademician Zuev Sq., Tomsk 634055, Russia;3. Department of Chemistry, Faculty of Science, University of Helsinki, FIN-00014 Helsinki, Finland;4. Groupe de Spectrométrie Moléculaire et Atmosphérique UMR CNRS 7331, UFR Sciences BP 1039, 51687 Reims Cedex 2, France
Abstract:The visible absorption spectrum of S2O vapor has been studied by spectrographic and laser optoacoustic techniques. Magnetic rotation spectroscopy was used to establish the triplet-singlet nature of the transition. Vibrational analysis gave ν1 = 1089, ν2 = 505, and ν3 = 332 cm−1.
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