Transition metal-catalyzed borylation of alkanes and arenes via C---H activation |
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Authors: | Tatsuo Ishiyama Norio Miyaura |
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Institution: | Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan |
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Abstract: | Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed C---H borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via C---H activation are summarized. |
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Keywords: | Transition metal complexes Bis(pinacolato)diboron Pinacolborane Hydrocarbon Organoboron compound C---H borylation |
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