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Neue Komplexe des Titans mit Bis(trimethylsilyl)amido-Liganden |
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| Authors: | Yü niu Bai,Herbert W. Roesky,Mathias Noltemeyer |
| Abstract: | New Complexes of Titanium with Bis(trimethylsilyl)amido Ligands The reaction of cp′TiCl3 with LiN(SiMe3)2 · Et2O 1 yield the compounds cp′TiCl2N(SiMe3)2 (cp′ = C5H5 2 , C5H4SiMe3 3 , C5H3(SiMe3)2 4 , C5Me5 5 ) and cp′TiCl[N(SiMe3)2]2 (cp′ = C5H5 6 ). Compound 2 was characterized by an X-ray structural analysis with space group P21/n and unit cell dimensions of a = 1 660.9(7), b = 688.6(3), c = 1 739.1(8) pm and β = 117.18(3)°. |
| Keywords: | Titanium complex compounds cyclopentadienyl titanium bis(trimethylsilyl)amido compounds syntheses crystal structure |