Fluorescence of Eu3+-doped InF3-based optical glasses |
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Affiliation: | 1. The Fourth Affiliated Hospital, The First Affiliated Hospital, Institute of Translational Medicine, School of Public Health, Cancer Center, State Key Laboratory of Experimental Hematology, Zhejiang University School of Medicine, Hangzhou 310058, China;2. Department of Anatomy, Biochemistry & Physiology, John A. Burns School of Medicine, University of Hawai‘i at Manoa, Honolulu, HI, USA;1. Department of Geography, The Ohio State University, 154 North Oval Mall, Columbus, OH, 43210, USA;2. Department of Geography and Planning, University of Toledo, 11 2801 W Bancroft St, Toledo, OH, 43607, USA;3. School of Earth, Environment & Society, McMaster University, 1280 Main Street West, Hamilton, Ontario, L8S 4K1, Canada |
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Abstract: | This paper reports physical, absorption and photoluminescence spectral properties of Eu3+-doped indium trifluoride-based optical glasses of the following formulae: 48 InF3-24 BaF2-7 AlF3-20 RF, where RF is the alkali content (LiF, NaF and KF). From fluorescence characteristics of these Eu3+-doped glasses, it is found that Glass-A with 20 M% LiF as the network modifier shows a better trend in its optical behaviour. A red emission from these glasses has been noticed upon illumination with the UV lamp. The lifetimes of the lasing transition (5D0→7F2) have been measured both at 300 and 77K with an Ar+ laser (487.9 nm) as the source of excitation. Four additional fluorescent levels at 580, 592, 598 and 653 nm have also been measured. |
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