Chemiluminescence upon isomerization of dimethyldioxirane in the gas phase and on a sorbent surface |
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Authors: | D V Kazakov A I Voloshin N N Kabal'nova V V Shereshovets V P Kazakov |
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Institution: | (1) Institute of Organic Chemistry, Ufa Scientific Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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Abstract: | Chemiluminescence (CL) was found upon the isomerization of dimethyldioxirane in the gas phase under argon atmosphere. The intensity of CL increases as temperature increases and decreases with time at constant temperature. If Silipor is placed in a cell containing the dimethyldioxirane vapor in argon, the intensity of CL sharply increases (more than 10 times) and then decreases following the exponential law. In all cases tripletly excited methyl acetate is the emitter of chemiluminescence./ p]Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2582–2583, October 1996. |
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Keywords: | isomerization dimethyldioxirane chemiluminescence gas phase |
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