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Antiradical activity of aryl- and hetarylhydrazones in ethylbenzene oxidation |
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| Authors: | E. I. Khizhan V. V. Vinogradov V. V. Morenko A. N. Nikolaevskii A. I. Khizhan O. M. Zarechnaya A. F. Dmitruk |
| Affiliation: | 1. Donetsk National University, ul. Universitetskaya 24, Donetsk, 83001, Ukraine 2. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, Ukraine 3. Michael Tugan-Baranovsky Donetsk National University of Economy and Trade, Donetsk, Ukraine |
| Abstract: | A relation between the kinetic parameters of the antiradical activity of aryl and hetarylhydrazones and their electronic structure is revealed in the form of the correlation between the reaction rate constants, bond energies of the reaction centers and the antioxidants ionization potentials. The relations obtained can be used to predict the antiradical activity in a series of hydrazones. |
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