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Trinuclear rhodium hydride complexes
Authors:Fischer Christian  Kohrt Christina  Drexler Hans-Joachim  Baumann Wolfgang  Heller Detlef
Affiliation:Leibniz-Institut für Katalyse e.V. an der Universit?t Rostock, Albert-Einstein-Stra?e 29a, 18059, Rostock, Germany.
Abstract:Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H](3)(μ(2)-H)(3)(μ(3)-H)}[BF(4)](2) containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.
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